The three correct options are pH 1 - random coil, pH 7 - helix and pH 11 - random coil.
At a pH of 1, the solution is acidic and the lysine residues will be mostly positively charged. The positive charges on the amino groups can lead to repulsion between neighboring lysine residues, making it energetically unfavorable for the polymer chain to adopt an alpha-helical conformation. Therefore, at a pH of 1, the conformation of polylysine is likely to be a random coil.
At a pH of 7, which is close to the physiological pH of most living organisms, the amino and carboxyl groups in lysine residues are mostly neutral, allowing the polymer chain to adopt a more stable alpha-helical conformation.
At a pH of 11, the solution is basic and the lysine residues will be mostly negatively charged. This can lead to repulsion between neighboring lysine residues and prevent the formation of an alpha-helical conformation. Therefore, at a pH of 11, the conformation of polylysine is likely to be a random coil.
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The complete question is :
A Homopolymer Of Lysine Residues (Polylysine) Can Adopt An Alpha-Helical Conformation Or A Random Coil Conformation Depending On The PH Of The Solution. Predict Whether The Conformation Of Polylysine Would Be Alpha-Helical Or Random Coil At A PH Of 1, 7, And 11. (Choose A Total Of THREE Answers. Choose Either Helix Or Random Coil For PH 1, PH 7, And PH
A homopolymer of lysine residues (polylysine) can adopt an alpha-helical conformation or a random coil conformation depending on the pH of the solution. Predict whether the conformation of polylysine would be alpha-helical or random coil at a pH of 1, 7, and 11. (Choose a total of THREE answers. Choose either helix or random coil for pH 1, pH 7, and pH 11).
options:
pH 1 - helix
pH 1 - random coil
pH 7 - helix
pH 7 - random coil
pH 11 - helix
pH 11 - random coil
list three initiators and three monomers for radical polymerization to build up polymers (including the reaction conditions).
The maximum extensively used initiators produce unfastened radicals (reactive atoms or organizations of atoms that include bizarre numbers of electrons).
Examples encompass peroxides and aliphatic azo compounds used to polymerize vinyl chloride, methyl methacrylate, and different monomers. Radical polymerization of vinyl monomers (styrene, methyl methacrylate, and vinyl acetate) changed into done in diverse nanochannels of porous coordination polymers (PCPs), wherein relationships among the channel length and polymerization behaviors, which include monomer reactivity, molecular weight, and stereostructure. Radical initiators are applied in business methods which include polymer synthesis. Typical examples are molecules with a nitrogen-halogen bond, azo compounds, and natural and inorganic peroxides.
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At a certain temperature, the equilibrium constant, Kc, for this reaction is 53.3.
H2 (g) + I2 (g) <----> 2HI (g) Kc=53.3
At this temperature, 0.500 mol of H2 and 0.500 mol of I2 were placed in a 1.00-L container to react. What concentration of HI is present at equilibrium?
HI = ....M
The concentration of HI present at equilibrium is 0.516 M when 0.500 mol of H2 and 0.500 mol of I2 were placed in a 1.00-L container to react.
The balanced chemical equation for the reaction is:
H2 (g) + I2 (g) ⇌ 2HI (g)
The initial molar concentrations are:
[H2] = 0.500 mol/1.00 L = 0.500 M
[I2] = 0.500 mol/1.00 L = 0.500 M
[HI] = 0 M (since there is no HI initially)
Let x be the change in concentration of H2, I2 and HI at equilibrium. Since 2 mol of HI is formed for every 1 mol of H2 or I2 reacted, the equilibrium concentrations can be expressed as:
[H2] = 0.500 - x
[I2] = 0.500 - x
[HI] = 2x
Substitute these expressions into the equilibrium constant expression:
[tex]Kc = [HI]^2 / ([H2] *[I2])[/tex]
[tex]53.3 = (2x)^2 / ((0.500 - x) * (0.500 - x))[/tex]
Solving for x using quadratic formula gives x = 0.258 M.
Therefore, the concentration of HI at equilibrium is:
[HI] = 2x = 2(0.258) = 0.516 M.
So the concentration of HI present at equilibrium is 0.516 M.
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for each of the following pairs, predict which substance is more soluble in water. substance 1 compares to substance 2 ch3cho ch3ch2ch3 ch3co2h ch3(co)och3 (ch3)3cch2oh ch3(ch2)6oh ch3(ch2)4cooh (ch3)3ccooh ch3ch2oh ccl4 ch3oh ch3ch2oh
The soluble in water substances are:Ch3CHO is more soluble in water than CH3CH2CH3.
Ch3CO2H is more soluble in water than (CH3)3COCH3.
(CH3)3CCH2OH is more soluble in water than CH3(CH2)6OH.
In comparison to (CH3)3CCOOH, CH3(CH2)4COOH is more soluble in water.
CH3CH2OH is more soluble in water than CCl4.
CH3OH is more soluble in water than CH3CH2OH.
Ch3CHO (Acetaldehyde) is more soluble in water than Ch3CH2CH3 (Propane). This is due to Acetaldehyde containing a polar C=O bond which is hydrogen bonding with water molecules and is thus more soluble.
Ch3CO2H (Acetic Acid) is more soluble in water than Ch3(CO)OCH3 (Acetone). This is due to Acetic Acid containing an acidic hydrogen atom which is hydrogen bonding with water molecules and is thus more soluble.
(CH3)3CCH2OH (2-Methyl-2-propanol) is more soluble in water than Ch3(CH2)6OH (Hexanol). This is due to 2-Methyl-2-propanol containing a polar OH bond which is hydrogen bonding with water molecules and is thus more soluble.
Ch3(CH2)4COOH (Butyric Acid) is more soluble in water than (CH3)3CCOOH (2,2-Dimethylpropionic Acid). This is due to Butyric Acid containing an acidic hydrogen atom which is hydrogen bonding with water molecules and is thus more soluble.
Ch3CH2OH (Ethanol) is more soluble in water than CCl4 (Carbon Tetrachloride). This is due to Ethanol containing a polar OH bond which is hydrogen bonding with water molecules and is thus more soluble.
Ch3OH (Methanol) is more soluble in water than Ch3CH2OH (Ethanol). This is due to Methanol containing a strong hydrogen bond which is hydrogen bonding with water molecules and is thus more soluble.
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Draw the structure of the major organic product of the reaction below.CH3​CH2​OCH2​CH2​CH=CH2​+CH2​I2​ Zn(Cu)/ether. ​−- Use the wedge/hash bond tools to indicate stereochemistry where it exists. - Show stereochemistry in a meso compound. - If the reaction produces a racemic mixture, just draw one stereoisomer.
The major organic product of the reaction is a disubstituted dihalomethane, with a structure of [tex]CH3-CH(CH3)-CH-I-CH3[/tex]. This compound is optically inactive, and thus a meso compound.
The reaction of [tex]CH3-CH(CH3)-CH=CH2[/tex] with [tex]CH2I2[/tex] upon reacting with Zn(Cu) produces a meso compound, meaning that the molecule contains two or more identical groups attached to opposite sides of a stereocenter. Stereochemistry is not applicable here, so the structure does not need to be drawn with wedge/hash bonds. The reaction produces a racemic mixture, which means that the product is an equal mixture of two stereoisomers that are mirror images of each other. As such, since only one stereoisomer needs to be drawn, the structure of [tex]CH3-CH(CH3)-CH-I-CH3[/tex] is sufficient to represent the major organic product.
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Classify the strongest type of intermolecular force in the following interactions: solvent-solvent, solvent-solute, and solute-solute when solid glucose (C6H12O6) is placed in the water. Drag the terms on the left to the appropriate blanks on the right to complete the sentences
hydrogen bonding
dipole-dipole forces
London dispersion forces
ion-dipole forces
Solute-solute is .
Solvent-solvent is .
Solvent-solute is .
please fill one sentence for each blank
The interaction between polar water molecules and the partially charged ions of glucose, resulting in ion-dipole forces, is the strongest inter molecular force in the solvent-solute interaction.
What is the solute interaction?Solute interaction is the interaction between two or more solutes in a solution. This interaction can be either physical or chemical in nature. Physical interactions involve the solutes having an effect on each other due to their shape, size or charge. Chemical interactions involve the solutes reacting with each other to form new compounds. In either case, the solutes will have an effect on the properties of the solution such as viscosity, boiling point, freezing point, and solubility. Solutes can also interact with each other when they are mixed together, as in a mixture of two liquids or a mixture of two solids.
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Two different substances contain molecules of similar molar mass. However, one substance exhibits hydrogen bonding, while the other does not. Which of the following statements is true?
A. Both substances will have the same viscosity.
B. The substance that contains molecules that exhibit hydrogen bonding is non-polar.
C. The substance with molecules that do not exhibit hydrogen bonding will have a lower vapor pressure than the substance with molecules that do not exhibit hydrogen bonding.
D. The substance with molecules that exhibit hydrogen bonding will have a higher boiling point than the substance with molecules that do not exhibit hydrogen bonding.
It is true that the substance with hydrogen-bonded molecules will have a greater boiling point than the substance with non-hydrogen-bonded molecules.
Which substance will have molecules bound together by hydrogen?Hydrogen bonds can form in any molecule where an oxygen or nitrogen atom is directly connected to a hydrogen atom. Despite the absence of the HF group in other compounds, hydrogen bonds can still form when hydrogen is linked to fluorine.
What circumstances would hydrogen bonding exist in?An electronegative atom from another molecule, such as nitrogen, oxygen, or fluorine, interacts with a hydrogen atom to form a hydrogen bond. To establish the link, the hydrogen has to build a covalent bond with an additional electronegative atom.
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compare current renewable and non-renewable energy sources with statistics quantity available, cost, sustainability, pollution factor, safety factor
Renewable resources are defined as resources that cannot be depleted over time. Non-renewable resources are defined as resources that are deplete over time.
Renewable energy is defined as the energy that is derived from natural sources that are replenished at a higher rate than they are consumed. For example sunlight and wind are such sources that are constantly being replenished. Renewable energy sources are present plentiful and are available all around us. The cost of renewable energy sources are less in comparison to non-renewable energy sources. Renewable sources usually are pollution free and safe towards human life.
Non-renewable energy is defined as the energy that comes from sources that will run out or will not be replenished in our lifetimes, or even in many, many lifetimes. Most of the non-renewable energy sources are fossil fuels which includes coal, petroleum, and natural gas. Non-renewable energy sources are available in limited quantity. Non-renewable energy sources are comparably more costly than renewable resources. Coals, petroleum and natural resources usually increases pollution and are harmful to human being.
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s 6 hno3 --> h2so4 6 no2 2 h2o in the above equation how many grams of water can be made when 8 grams of hno3 are consumed? use the following molar masses. if yo
For the given chemical equation, 8 grams of HNO₃ will produce 0.76 grams of water.
The chemical reaction is:
S + 6 HNO₃ → H₂SO₄ + 6 NO₂ + 2 H₂O
From the table we know that:
molar mass H = 1
molar mass N = 14
molar mass O = 16
Molar mass of water (H₂O) = 2 x molar mass H + molar mass O
= 2 + 16 = 18 gram/mole
Molar mass of HNO₃ = 1 + 14 + 3 x 16 = 63 gram/mole
8 gram HNO₃ is equivalent to 8/63 moles
6 moles HNO₃ produce 2 moles water
8/63 moles HNO₃ will produce (2/6) x (8/63) moles water
(2/6) x (8/63) moles H₂O is equivalent to (2/6) x (8/63) x 18 gram, which equals 0.76 gram water.
Your question is incomplete, most likely it was:
S + 6 HNO₃ → H₂SO₄ + 6 NO₂ + 2 H₂O
In the above equation how many grams of water can be made when 8 grams of hno3 are consumed? use the following molar masses
Element Molar Mass
Hydrogen 1
Nitrogen 14
Sulfur 32
Oxygen 16
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when an electron jumps from a larger orbit to a smaller orbit within an atom, it changes from a energy level to a energy level and a photon is .
The electron changes from a higher energy level to a lower energy level, and a photon is emitted.
What is electrons?
Electrons are the smallest and most fundamental particles that make up matter. They are negatively charged particles that exist in the orbits of atoms and molecules and that participate in chemical reactions. Electrons are found in all atoms, and determine the chemical properties of the atom. They are also responsible for electricity and magnetism, and can be used to create electrical current in circuits. Electrons have a very small mass and move around the nucleus of an atom very quickly. In addition, electrons can be excited by certain energies, causing them to move to higher energy levels, where they can then be used to create electrical current.
Therefore, The electron changes from a higher energy level to a lower energy level, and a photon is emitted.
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Describe the biochemical role of coenzyme Q10 and how supplementation may impact metabolism. Be sure to address the key terms listed below as part of your discussion; you may address additional etiologies as well. • coenzyme Q
• Electron transport chain • Complex II • Reactive oxygen species • Complex I
• Oxidative phosphorylation
• Complex III
• ubiquinone
• ubiquinol
Coenzyme Q10's main biochemical function is as a cofactor in the electron-transport chain, which is one of the series of redox processes required for the creation of adenosine triphosphate.
What is coenzyme ?A coenzyme is a chemical that collaborates with an enzyme to start or support the enzyme's operation. It may be viewed as a supporting molecule in a biological process.
Coenzyme Q10 is crucial for the functioning of all human tissues and organs since the majority of cellular processes depend on an appropriate supply of adenosine triphosphate (ATP).
A fat-soluble substance produced by the body, coenzyme Q10 can only be found in trace amounts in the food.
Coenzyme Q10 is essential for the formation of adenosine triphosphate and mitochondrial oxidative phosphorylation (ATP).
While its amount in our bodies declines with advancing age, it is crucial for optimum bodily functioning and must be consumed through a healthy diet.
Coenzyme Q10 regulates the different mediated inhibition, which enhances lipid metabolism and reduces obesity.
Thus, sufficient Q10 consumption prevents oxidative stress and delays the progression of aging.
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Use relative differences in electronegativity to label the ends of the polar molecules feted as partially positive or partially negative. a. HF b. HBr c. NO d. CO
Labeling of the ends of the polar molecules feted as partially positive or partially negative are:
a. The difference in electronegativity between H and F is relatively high (around 1.9), so the bond is quite polar. F is more electronegative than H, so the fluorine end is partially negative and the hydrogen end is partially positive.
b. The difference in electronegativity between H and Br is moderate (around 0.7), so the bond is somewhat polar. Br is more electronegative than H, so the bromine end is partially negative and the hydrogen end is partially positive.
c. The difference in electronegativity between N and O is relatively small (around 0.5), so the bond is somewhat polar. O is more electronegative than N, so the oxygen end is partially negative and the nitrogen end is partially positive.
d. The difference in electronegativity between C and O is relatively large (around 1.0), so the bond is quite polar. O is more electronegative than C, so the oxygen end is partially negative and the carbon end is partially positive.
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I need to know this question
The balanced chemical equation of the above reaction with the coefficients are as follows:
2CO₂ + 3H₂O → C₂H₅OH + 3O₂
What is a balanced equation?A chemical equation is said to be balanced when the number of atoms of each element on both sides of the equation are the same.
Coefficients are used to balance chemical equation by placing them in front of the substances involved in the reaction.
According to this question, carbondioxide reacts with water to produce ethanol and oxygen gas as follows:
2CO₂ + 3H₂O → C₂H₅OH + 3O₂
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for a 0.18m solution fo hno3, calculate [h }, ph, poh, and [oh-} determine all ph and poh values to two decimal places
HNO3 is a strong acid that dissociates completely in water, producing H+ and NO3- ions. Therefore, in a 0.18 M solution of HNO3, the concentration of H+ is also 0.18 M.
[H+] = 0.18 M
To calculate the pH of the solution, we use the formula:
pH = -log[H+]
pH = -log(0.18)
pH = 0.74
To calculate the pOH of the solution, we use the fact that pH + pOH = 14:
pOH = 14 - pH
pOH = 14 - 0.74
pOH = 13.26
To calculate the concentration of OH- ions, we use the formula:
[OH-] = Kw / [H+]
where Kw is the ion product constant of water, which is 1.0 × 10^-14 at 25°C.
[OH-] = 1.0 × 10^-14 / 0.18
[OH-] = 5.56 × 10^-14 M
Therefore, the [OH-] concentration is 5.56 × 10^-14 M.
To check our results, we can verify that pH + pOH = 14:
pH + pOH = 0.74 + 13.26 = 14.00
Therefore, our results are consistent with each other and with the principles of acid-base chemistry.
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What type of radiation is released during this reaction?
This radiation can be emitted in the form of positively charged alpha particles, negatively charged beta particles, gamma rays, or x-rays, as explained below.
What is a gamma rays simple definition?Gamma rays are a type of electromagnetic radiation that results from a redistribution of electric charge within a nucleus. Gamma rays are essentially very energetic X rays ; the distinction between the two is not based on their intrinsic nature but rather on their origins.
Who invented gamma rays?chemist Paul Villard Gamma radiation is one of the three types of natural radioactivity discovered by Becquerel in 1896. Gamma rays were first observed in 1900 by the French chemist Paul Villard when he was investigating radiation from radium .
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Write the equation that models the alpha decay for plutonium-240.
Answer:
Explanation:
240 4 236
Pu ----> He + U
94 2 92
What are the answers to the following 5 multiple choice questions
The balanced equation of the reaction is option d. The limiting reactant here is KBr and excess reactant is calcium nitrate. The percent yield of the reaction is 93 %.
What is limiting reactant ?The limiting reactant in a reaction is the reactant which is fewer in amount and as soon it is consumed, the reaction stops. For the given reaction, option d is the balanced chemical equation.
One mole of calcium nitrate requires 2 moles of KBr.
molar mass of calcium nitrate = 164 g/mol
no.of moles in 75 g = 75/164 = 0.457
molar mass of KBr = 118.9 g/mol
no.of moles 95 g = 95/118.9 = 0.798
0.457 moles of calcium nitrate needs its twice amount that is 0.9 moles of KBr. Hence, KBr is the limiting reactant and calcium nitrate is excess reactant here.
2 moles or 237.8 g of KBr gives 2 moles or 202 g of potassium nitrate. Then, 95 g of KBr will gives:
(95×202)/237.6 = 81.3 g
actual yield = 75.75 g
then percent yield = 75.75 /81.3 × 100 = 93 %.
0.79 moles of KBr needs its half or 0.399 moles of calcium nitrate. But we have 0.45 moles. Thus, excess amount is
(0.45 - 0.399) × 164 g/mol = 9.5 g.
Therefore, the 9.5 g of excess reactant will be left over.
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Provide the quantum numbers and related information for the following orbital, 4f.
What is the principal quantum number, n?
What is the angular momentum quantum number, l?
What is the number of degenerate orbitals based on the magnetic quantum number?
How many radial nodes are there?
What is the maximum number of electrons in the entire shell?
The principal quantum number is n = 4. Angular momentum quantum number l = 3. The number of degenerate orbitals based on the magnetic quantum number is 7 . The number of radial nodes is 0 .
maximum number of electrons in the entire shell are 14.
The 4f orbital is a sublevel of the fourth energy level, so the principal quantum number is n = 4.
The angular momentum quantum number, l, is equal to 3 for the f subshell. This means that the electrons in the 4f orbital have l = 3.
For the magnetic quantum number, ml, the range is -l to +l, so for the 4f orbital, there are 2l + 1 = 7 possible values of ml (-3, -2, -1, 0, 1, 2, 3), which means there are 7 degenerate orbitals.
The number of radial nodes can be calculated using the formula n - l - 1, so for the 4f orbital, there are (4 - 3 - 1) = 0 radial nodes.
The maximum number of electrons in the entire shell can be determined using the formula 2n^2, where n is the principal quantum number. For n = 4, the maximum number of electrons in the 4th shell is 2(4)^2 = 32. However, since the 4f orbital is a sublevel within the 4th shell, the maximum number of electrons that can occupy the 4f orbital is given by the Pauli exclusion principle, which states that no two electrons in an atom can have the same set of four quantum numbers. Therefore, the maximum number of electrons that can occupy the 4f orbital is 2 x 7 = 14.
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What is the molarity of a solution that contains 9.10 g of NH3 in 0.38 L of solution?
The most common way to express solution concentration is the molarity
What is the molality of a solution?The molality of a solution is uniform to the moles of solute divided by the mass of solvent in kilograms, while the molarity of a solution is alike to the moles of solute divided by the volume of solution in liters.
Molarity is the number of moles of solute per liter of solution. For example, if you dissolve table salt in water, salt is the solute, and water is the solution. One mole of sodium chloride weighs 58.44 grams. If you diffuse 58.44 grams of NaCl in one liter of water, you have a one-molar solution, reduced to 1M
So we can conclude that Molarity is defined as the integer of moles of solute per liter of solution.
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in one trial, you dissolve 0.1052 g of na2co3 in approximately 25 ml of water. titrating with your solution of hcl requires 13.23 ml to reach the equivalence point. report the molar concentration of hcl to the correct number of significant figures. your solution of hcl is lot number b5.
Rounding to the correct number of significant figures, the molarity of the HCl solution is 0.150 mol/L.
The balanced chemical equation for the reaction between sodium carbonate (Na2CO3) and hydrochloric acid (HCl) is:
Na2CO3 + 2 HCl → 2 NaCl + H2O + CO2 :From the equation, we can see that 2 moles of HCl are required to react with 1 mole of Na2CO3.
First, we need to determine the number of moles of HCl used in the titration:
moles of HCl = volume of HCl (in L) × molarity of HCl
We know the volume of HCl used in the titration is 13.23 mL, or 0.01323 L. We need to find the molarity of the HCl solution to determine the number of moles of HCl used.
To do this, we need to know the mass of Na2CO3 used in the titration and the balanced chemical equation to find the number of moles of Na2CO3:
molar mass of Na2CO3 = 2 × atomic mass of Na + atomic mass of C + 3 × atomic mass of O
= 2 × 22.99 g/mol + 12.01 g/mol + 3 × 16.00 g/mol
= 105.99 g/mol
moles of Na2CO3 = mass of Na2CO3 / molar mass of Na2CO3
= 0.1052 g / 105.99 g/mol
= 0.000992 mol
Since 2 moles of HCl are required to react with 1 mole of Na2CO3, the number of moles of HCl used in the titration is:
moles of HCl = 2 × moles of Na2CO3
= 2 × 0.000992 mol
= 0.001984 mol
Now we can calculate the molarity of the HCl solution:
molarity of HCl = moles of HCl / volume of HCl (in L)
= 0.001984 mol / 0.01323 L
= 0.1499 mol/L
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the phenol used in some mouthwashes and throat lozenges is . selected answer: correctc. hexylresorcinol answers: a. cannabinol b. cresol correctc. hexylresorcinol d. hexachlorophene
The correct answer to the question about the phenol used in some mouthwashes and throat lozenges is option C, hexylresorcinol.
This compound is a type of phenol that is used as an antiseptic and disinfectant in various products, including mouthwashes and throat lozenges.
It is effective in killing bacteria and other microorganisms that can cause infections and other health problems.
Therefore, the correct answer to this question is hexylresorcinol.
Hexylresorcinol is a substituted phenol with bactericidal, antihelminthic and potential antineoplastic activities.
Hexylresorcinol is used as an antiseptic in mouthwashes and skin wound cleansers.
The antibacterial effects of hexylresorcinol in vivo may be mediated through several mechanisms including reducing bacterial adherence to the pharynx, inhibiting bacterial biofilm formation, disrupting bacterial cell chain formation, and modifying cell surface hydrophobicity
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write structural formulas for four compounds with the formula c3h6o, and classify each according to its functional group. predict ir absorption frequencies for the functional groups you have drawn.
The O- group is a special type of oxygen-containing functional group called an ether. The oxygen atom of the ether group is bonded to two carbon atoms, so the IR absorption frequency for this functional.
What is the carbon atoms?Carbon atoms are the basic building blocks of organic molecules and are essential to all known forms of life. Carbon atoms are a unique element because they have the ability to form strong bonds with other elements, such as hydrogen, oxygen and nitrogen. This allows them to form an incredibly wide variety of molecules, from simple sugars to complex proteins.
1. Ethanol (Alcohol): C3H6O
Functional Group: OH (Hydroxyl), IR Absorption Frequency: 3350 cm-1
2. Acetone (Ketone): C3H6O
Functional Group: C=O (Carbonyl), IR Absorption Frequency: 1715 cm-1
3. 2-Propanol (Alcohol): C3H6O
Functional Group: OH (Hydroxyl), IR Absorption Frequency: 3350 cm-1
4. Dimethyl Ether (Ether): C3H6O
Functional Group: O- (Ether), IR Absorption Frequency: 1090 cm-1
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Scottish physician and chemist William Cullen introduced bonding brackets and ____ to enable chemists to pictorially represent affinity reactions, and develop chemical reaction equations.
Scottish physician and chemist William Cullen introduced bonding brackets and affinity arrows to enable chemists to pictorially represent affinity reactions, and develop chemical reaction equations.
What did William Cullen introduce?William Cullen was a Scottish physician and chemist who lived from 1710 to 1790. He made significant contributions to the field of chemistry, including the development of the theory of "affinity," which helped explain chemical reactions.
Cullen's ideas were important precursors to the modern understanding of chemical bonding and reactions. His use of arrows to represent affinity is similar to the modern use of arrows to represent electron movement in chemical reactions. His use of brackets to represent the structure of molecules is also similar to modern notation.
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An average reaction rate is calculated as the change in the concentration of reactants or products over a period of time in the course of the reaction. An instantaneous reaction rateis the rate at a particular moment in the reaction and is usually determined graphically.
The reaction of compound A forming compound B was studied and the following data were collected:
Time (s) [A] (M)
0. 0.184
200. 0.129
500. 0.069
800. 0.031
1200. 0.019
1500. 0.016
Part A: What is the average reaction rate between 0. and 1500. s? Express your answer to three significant figures and include the appropriate units.
Part B: What is the average reaction rate between 500. and 1200. s ? Express your answer to three significant figures and include the appropriate units.
Part C: What is the instantaneous rate of the reaction at t=800. s? Express your answer to two significant figures and include the appropriate units.
The average reaction rate between 0 and 1500 s is -0.000105 M/s and the average reaction rate between 500 and 1200 s is -0.0000571 M/s
Part A: To calculate the average reaction rate, we can use the formula:
Average rate = (change in concentration)/(change in time)
The change in concentration of A is [A]t - [A]0, and the change in time is t - 0. Using the given data, we get:
Average rate = ([A]1500 - [A]0)/(1500 - 0) = (0.016 - 0.184)/(1500) = -0.000105 M/s
Therefore, the average reaction rate between 0 and 1500 s is -0.000105 M/s.
Part B: Following the same formula as above, we can calculate the average rate between 500 and 1200 s using the given data:
Average rate = ([A]1200 - [A]500)/(1200 - 500) = (0.031 - 0.069)/(700) = -0.0000571 M/s
Therefore, the average reaction rate between 500 and 1200 s is -0.0000571 M/s.
Part C: The instantaneous rate at t=800 s can be determined by drawing a tangent to the concentration vs. time plot at that point and finding its slope.
From the given data, we can plot [A] vs. time and draw a tangent at t=800 s
The slope of this tangent gives us the instantaneous rate at that point. Using a straight edge or ruler, we can estimate the slope to be approximately -0.0000575 M/s.
Therefore, the instantaneous rate of the reaction at t=800 s is approximately -0.0000575 M/s.
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A student is provided an unknown hydrocarbon and perform a combustion experiment. Visually the result of the combustion experiment is a yellow flame that is not very intense and produced a small amount of smoke. Using techniques not discussed in the lab the student found that the combustion reaction produced 6 moles of carbon dioxide and 6 moles of water and that it is less than 5 carbons. Identify the name of the hydrocarbon used in this experiment and calculate the volume (mL) of the hydrocarbon starting material
The volume of the butane starting material is 24500 mL, or 24.5 liters.
We use the balanced chemical equation for the combustion of a hydrocarbon to determine the number of moles of the hydrocarbon that were used in the experiment:
Hydrocarbon + O₂ → CO₂ + H₂O
We know that 6 moles of CO₂ and 6 moles of H₂O were produced. This means that the hydrocarbon contained 6 carbon atoms (since each mole of CO₂ produced in the reaction comes from one carbon atom in the hydrocarbon).
Since we also know that the hydrocarbon has less than 5 carbons, this means that it must be either propane (C₃H₈) or butane (C₄H₁₀).
To determine which of these two hydrocarbons was used, we can calculate the theoretical yield of CO₂ for each one and compare it to the actual yield of 6 moles.
For propane, the theoretical yield of CO₂ would be 3 moles, while for butane, it would be 4 moles. Since the actual yield was 6 moles, it is more likely that butane was the hydrocarbon used.
To calculate the volume of the butane starting material, we need to use the ideal gas law:
PV = nRT
Rearranging the equation, we get:
V = nRT/P = (1 mol)(0.0821 L·atm/mol·K)(298 K)/(1 atm) = 24.5 L
Since the volume is in milliliters (mL), we can convert:
24.5 L x 1000 mL/L = 24500 mL
Therefore, the volume of the butane starting material is 24500 mL, or 24.5 liters.
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When a spherical droplet of liquid is sheared into much finer droplets, which of the following statement is correct for the final droplets?
please explain your answer
a. The sum of the radii of all the droplets will be equal to the radius of the initial droplet
b. The mass of a single final droplet is same as that the initial droplet
c. The sum of the volume of all the final droplets is same as that of the initial droplet
d. The sum of the surface area of final droplets is same as that of the initial droplet
The sum of the volume of all the final droplets is the same as that of the initial droplet. So option C is correct.
When a spherical droplet of liquid is sheared into much finer droplets, the total volume of the initial droplet is conserved, but it is distributed among a greater number of smaller droplets.
Since volume is conserved, the sum of the volumes of all the final droplets is equal to the volume of the initial droplet.
Option a is incorrect because the sum of the radii of all the droplets will be greater than the radius of the initial droplet since the total surface area has increased due to the formation of additional droplets.
Option b is incorrect because when a droplet is sheared, it breaks up into smaller droplets, so the mass of each individual droplet will be less than the mass of the initial droplet.
Option d is incorrect because the surface area of the final droplets will be greater than the surface area of the initial droplet, as there are more droplets with a greater surface area in total.
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Which of the following structural features allow an alcohol to exhibit intermolecular hydrogen bonding? Select all that apply. Check all that apply. The presence of hydrogen atoms bonded to carbon The polar bond between oxygen and carbon The presence of nonbonding electron pairs on the oxygen atom A hydrogen atom bonded to a highly electronegative oxygen atom
An alcohol can display intermolecular hydrogen bonding if it has the following structural characteristics:
the oxygen atom having non-bonding electron pairs
An oxygen atom with a strong electronegative connection to a hydrogen atom
What is Bonding?
In chemistry, bonding refers to the formation of chemical bonds between atoms or molecules, resulting in the creation of a stable compound. Chemical bonding occurs when two or more atoms share, donate, or receive electrons in order to achieve a more stable electronic configuration.
The most common types of chemical bonding include covalent bonding, ionic bonding, and metallic bonding.
In covalent bonding, atoms share one or more pairs of electrons to form a molecule. Covalent bonds can be polar or nonpolar, depending on the electronegativity difference between the atoms.
In ionic bonding, one or more electrons are transferred from one atom to another, resulting in the formation of positive and negative ions that are attracted to each other.
These two features allow alcohols to form strong intermolecular hydrogen bonds between neighboring alcohol molecules. The polar bond between oxygen and carbon and the presence of hydrogen atoms bonded to carbon are important features of alcohol molecules, but they do not directly contribute to the ability of alcohols to exhibit intermolecular hydrogen bonding.
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Brainly User
01/23/2022
Chemistry
High School
answered • expert verified
Vinegar (acetic acid) and baking soda (sodium bicarbonate) react in an endothermic reaction to produce sodium acetate, carbon dioxide, and water. Which statement justifies classifying the reaction as endothermic?
A. The reaction produces water.
B. The bonds in both the reactants and products are covalent bonds.
C. The reaction needs a catalyst.
D. The total potential energy of the products is less than the total potential energy of the reactants.
Vinegar (acetic acid) and baking soda (sodium bicarbonate) react in an endothermic reaction to produce sodium acetate, carbon dioxide, and water. The statement that justifies classifying the reaction as endothermic is The total potential energy of the products is less than the total potential energy of the reactants. The correct answer is D.
An endothermic process is one in which the heat of the system increases as a result of absorbing heat from the environment and transferring it to the system. The reactants have higher potential energy than the products.
Why do endothermic reactions occur?Baking soda and vinegar react by absorbing heat from the surrounding environment, resulting in the production of carbon dioxide, sodium acetate, and water.
The reactants in this kind of reaction absorb heat, increasing their potential energy, which is high in comparison to the potential energy of the products created.
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Write symbols for four elements that may have ions with the following electron configuration: 1s22s22p6. (Include the charge of the ion with the symbol. For example, if "Ca2+" is the correct answer enter "Ca2+" in the box.) Write the most positive ion first and the most negative ion last.
The electron configuration 1s22s22p6 corresponds to the noble gas neon (Ne), which has a completely filled valence shell.
What is Electric Configuration?
The placement of electrons around the nucleus of a specific atom or molecule is known as its electronic configuration.
Protons, neutrons, and electrons are the minuscule components that make up an atom. There are the same number of protons and electrons in a neutral atom. The quantity and location of an atom's electrons are revealed by its electronic configuration.
We say that electrons orbit the nucleus of an atom, like the rings of Saturn orbit the planet. Electrons move in orbitals that can accommodate a specific number of electrons as they circle the nucleus.
Four elements that may have ions with this electron configuration are:
Fluorine (F-) - gains one electron to achieve a noble gas configuration (1s22s22p6)
Oxygen (O2-) - gains two electrons to achieve a noble gas configuration (1s22s22p6)
Sodium (Na+) - loses one electron from the valence shell to achieve a noble gas configuration (1s22s22p6)
Magnesium (Mg2+) - loses two electrons from the valence shell to achieve a noble gas configuration (1s22s22p6)
Therefore, the symbols for these ions are:
Na+, Mg2+, F-, O2-.
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One bit of evidence that the quantum mechanical model is "correct" lies in the magnetic properties of matter. Atoms with unpaired clectrons are attracted by magnetic fields and thus are said to exhibit paramagnetism. The degree to which this effect is observed as directly related to the number of unpaired electrons present in the atom It has a Consider the ground state electron configuration for C. Would this atom be expected to be paramagnetic, and how many unpaired electrons are present? upaired electron() b. Consider the ground state electron configuration for F Would this tot be expected to be paramagnetic, and how many unpaired electrons are present? unpaired electron(s) e Consider the ground-state electron configuration for Fe Would this atom be expected to be paramagnetic, and how many unpaired electrons are present? unpaired electron(s) d. Consider the ground-state electron configuration for Sb. Would this atom be expected to be paramagnetic, and how many unpaired electrons are present? It has It has It has unpaired electron(s). c. Consider the ground-state electron configuration for Rb Would this to be expected to be paramagnetic, and how many unpaired electrons are present? It has unpaired electron) f Consider the ground-state electron configuration for Re Would this atom be expected to be paramagnetic, and how many paired electrons are present? It has unpaired electron)
An atom's paramagnetic activity increases with the amount of unpaired electrons in its outermost shell.
What is meant by quantum mechanical model?According to the atom's quantum mechanical concept, there are specific orbitals, or three-dimensional regions of space, where electrons are more likely to be found. A set of four quantum numbers can be used to describe each electron's characteristics within the quantum atom.
The quantum mechanical or wave mechanical model, on which our current understanding of the atom is based, is one such model. An electron in an atom may only exist in a limited set of states or energies, which is akin to a standing wave.
Consider the number of unpaired electrons in each of the given atoms be: Li-1, N-3, Ni-2 and Te-2
At least one unpaired electron must be present in the valence shell of an atom for it to be paramagnetic. Due to the spin pairing of every electron in their outermost shells, Ba and Hg are not paramagnetic.
An atom's paramagnetic activity increases with the amount of unpaired electrons in its outermost shell.
The complete question is:
One bit of evidence that the quantum mechanical model is "correct" lies in the magnetic properties of matter. Atoms with unpaired electrons are attracted by magnetic fields and thus are said to exhibit Para magnetism. The degree to which this effect is observed is directly related to the number of unpaired electrons present in the atom. Consider the ground-state electron configuration for . Would this atom be expected to be paramagnetic, and how many unpaired electrons are present? It has unpaired electron(s). Consider the ground-state electron configuration for . Would this atom be expected to be paramagnetic, and how many unpaired electrons are present?
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Find the solubility product constant for lead (II) iodide if the concentration of I- is found to be 1.25x10-3 M when the solution is saturated.
Use this Ksp value to determine if a precipitate will form when 350 mL of 5.5x10-2 M lead (II) nitrate is mixed with 250 mL of 4.8x10-2 M sodium iodide.
Earlier calculations were made because the ion product (IP) is bigger than the Ksp value. [tex](1.5625 \times 10-9)[/tex] A precipitate will occur because the solution is supersaturated with PbI2.
What best define about solubility product constant?Ions are atoms or molecules that have an unequal number of electrons and protons, resulting in a net electrical charge.
Atoms are electrically neutral because they normally include an equal number of positively and negatively charged protons and electrons. Yet, an atom becomes an ion and acquires electrical charge when it absorbs or loses one or more electrons.
The solubility product constant (Ksp) expression for lead (II) iodide (PbI2) is:
[tex]Ksp = [Pb2+][I-]^2[/tex]
We know the concentration of I- is [tex]1.25 \times 10-3 M[/tex] When the solution is saturated, but we don't know the concentration of Pb2+.
However, we can assume that the solubility of PbI2 is low and that the concentration of Pb2+ is much less than [tex]1.25 \times 10-3 M[/tex]. Therefore, we can use the concentration of I- to calculate the Ksp as follows:
[tex]Ksp = [Pb2+][I-]^2[/tex]
[tex]Ksp = x(1.25\pm \times 10-3)^2[/tex]
[tex]Ksp = 1.5625 \pm \times 10-9x[/tex]
using this Ksp value, we must ascertain whether a precipitate will occur when 350 mL of [tex]5.5 \times 10-2 M[/tex] 250 mL of lead (II) nitrate (Pb(NO3)2) and
[tex]4.8 \times 10-2[/tex] M iodide of sodium (NaI).
We must first figure out the original Pb2+ and I- concentrations in the combined solution. Since [tex]Pb(NO3)^2[/tex]is a potent electrolyte that totally dissociates into the ions Pb2+ and NO3- in water. Hence, the initial Pb2+ concentration is:
[tex][Pb2+] = (5.5 \times 10-2 M) \times (0.350 L/0.6 L) = 3.208 \times 10-2 M[/tex]
Similar to this, NaI totally separates into Na+ and I- ions in water due to its strong electrolyte nature. As a result, I- has the following initial concentration:
[tex][I-] = (4.8 \times 10-2 M) \times (0.250 L/0.6 L) = 2.000 \times 10-2 M[/tex]
Now determine the mixed solution's PbI2 ion product (IP) as follows.
[tex]IP = [Pb2+][I-]^2[/tex]
[tex]IP = (3.208 \times 10-2 M)(2.000 \times 10-2 M)^2[/tex]
[tex]IP = 2.563 \times 10-8[/tex]
Therefore, the ion product (IP) exceeds the Ksp value that we previously determined. [tex](1.5625 \times 10-9)[/tex], a precipitate will form because the solution is supersaturated with PbI2.
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