If a sample is said to contain a 98.0% enantiomeric excess of the compound (+)-camphor, what would be the observed specific rotation if the pure (+)-camphor was found to have a rotation of 44.1?

Answers

Answer 1

Answer:

the observed specific rotation is 43.218

Explanation:

Given the data in the question;

percentage of enantiomeric excess = 98.0%

observed specific rotation = ? { represented by x }

specific rotation of pure compound = 44.1

Now, we know that;

% of enantiomeric excess = ( observed specific rotation / specific rotation of pure compound ) × 100%

so we substitute

98.0 % = ( x / 44.1 ) × 100%

0.98 = x / 44.1

x = 0.98 × 44.1

x = 43.218

Therefore, the observed specific rotation is 43.218


Related Questions

Please help me name these organic compounds

Answers

Answer:

Aldehydes and Ketones

Both aldehydes and ketones contain a carbonyl group, a functional group with a carbon-oxygen double bond. The names for aldehyde and ketone compounds are derived using similar nomenclature rules as for alkanes and alcohols, and include the class-identifying suffixes -al and -one, respectively:

In an aldehyde, the carbonyl group is bonded to at least one hydrogen atom. In a ketone, the carbonyl group is bonded to two carbon atoms:

As text, an aldehyde group is represented as –CHO; a ketone is represented as –C(O)– or –CO–.

In both aldehydes and ketones, the geometry around the carbon atom in the carbonyl group is trigonal planar; the carbon atom exhibits sp2 hybridization. Two of the sp2 orbitals on the carbon atom in the carbonyl group are used to form σ bonds to the other carbon or hydrogen atoms in a molecule. The remaining sp2 hybrid orbital forms a σ bond to the oxygen atom. The unhybridized p orbital on the carbon atom in the carbonyl group overlaps a p orbital on the oxygen atom to form the π bond in the double bond.

Like the C=OC=O bond in carbon dioxide, the C=OC=O bond of a carbonyl group is polar (recall that oxygen is significantly more electronegative than carbon, and the shared electrons are pulled toward the oxygen atom and away from the carbon atom). Many of the reactions of aldehydes and ketones start with the reaction between a Lewis base and the carbon atom at the positive end of the polar C=OC=O bond to yield an unstable intermediate that subsequently undergoes one or more structural rearrangements to form the final product (Figure 1).

Figure 1. The carbonyl group is polar, and the geometry of the bonds around the central carbon is trigonal planar.

The importance of molecular structure in the reactivity of organic compounds is illustrated by the reactions that produce aldehydes and ketones. We can prepare a carbonyl group by oxidation of an alcohol—for organic molecules, oxidation of a carbon atom is said to occur when a carbon-hydrogen bond is replaced by a carbon-oxygen bond. The reverse reaction—replacing a carbon-oxygen bond by a carbon-hydrogen bond—is a reduction of that carbon atom. Recall that oxygen is generally assigned a –2 oxidation number unless it is elemental or attached to a fluorine. Hydrogen is generally assigned an oxidation number of +1 unless it is attached to a metal. Since carbon does not have a specific rule, its oxidation number is determined algebraically by factoring the atoms it is attached to and the overall charge of the molecule or ion. In general, a carbon atom attached to an oxygen atom will have a more positive oxidation number and a carbon atom attached to a hydrogen atom will have a more negative oxidation number. This should fit nicely with your understanding of the polarity of C–O and C–H bonds. The other reagents and possible products of these reactions are beyond the scope of this chapter, so we will focus only on the changes to the carbon atoms:

How does the magnetic force vary with distance

Answers

Answer:

Magnetic force obeys an inverse square law with distance. ... If the distance between two magnets is doubled the magnetic force between them will fall to a quarter of the initial value. (F/4) If the distance between two magnets is halved the magnetic force between them will increase to four times the initial value.

Determine the mass in grams of 3.27 × 10²¹ atoms of arsenic. (The mass of one mole of arsenic is 74.92 g.)

Answers

Explanation:

74.92 g.

(The mass of one mole of arsenic is 74.92 g.

Sodium is a highly reactive metal and
chlorine is a toxic gas, but when they
come together the resulting material,
sodium chloride, is essential for life.
Which of the following is true when
sodium and chlorine are brought into
contact with one another?

Answers

Answer:

NaCl

Explanation:

[tex]na + cl > nacl[/tex]

This is also a salt

The volume of a fixed mass of gas at 2 atm pressure is 20L.What will be its volume if the pressure is increased 4 times without changing the temperature.

Answers

Answer:

The correct answer is - 5L.

Explanation:

From the ideal gas equation -

pv=nRT

p = pressure

v =volume

Here nRT is constant so

P would be inversely proportioned to v

So, p1/p2 = v2/v1

Putting values:

2/4(2) = v2/20 (p2 = 4 times of P1)

2/8 = v2/20

V2 = 5

Thus, the correct volume at new pressure would be - 5 L.

 

Plz help!!!! NO LINKS

Answers

Answer:

481.16 cm³

Explanation:

From the question given above, the following data were obtained:

Height (h) = 11.72 cm

Diameter (d) = 7.23 cm

Pi (π) = 3.14159

Volume of cylinder (V) =?

Next, we shall determine the radius. This can be obtained as follow:

Diameter (d) = 7.23 cm

Radius (r) =?

r = d/2

r = 7.23 / 2

r = 3.615 cm

Finally, we shall determine the volume of the cylinder. This can be obtained as shown below:

Height (h) = 11.72 cm

Pi (π) = 3.14159

Radius (r) = 3.615 cm

Volume of cylinder (V) =?

V = πr²h

V = 3.14159 × 3.615² × 11.72

V = 3.14159 × 13.068225 × 11.72

V = 481.16 cm³

Therefore, the volume of the cylinder is 481.16 cm³.

Compound EX4 reacts with Y2 giving two products: EX Y and XY. Calculate the E- X bond enthalpy if the reaction liberates 243.6 kJ/mol and other bond enthalpies are:
Y-Y 109 kJ/mol,
X-Y 123.1 kJ/mol and
E-Y 290 kJ/mol.
a. 547.7 kJ/mol
b. 60.5 kJ/mol
c. 234.7 kJ/mol
d. 20.6 kJ/mol
e. 176.9 kJ/mol

Answers

Answer:

Option B

Explanation:

From the question we are told that:

Equation

[tex]EX_4+Y_2->EX_3Y+XY[/tex]

Bond enthalpies are:

 [tex]Y-Y 109 kJ/mol,[/tex]

[tex]X-Y 123.1 kJ/mol[/tex]  

[tex]E-Y 290 kJ/mol.[/tex]

Generally the equation for the energy used to break E-X and Y-Y is mathematically given by

 [tex]E_2=109+x[/tex]

Therefore

Total Energy Liberated is

 [tex]E_T=E_1+E_2[/tex]

 [tex]E_T=413.1+109+x[/tex]

 [tex]E_T=304.1-x[/tex]

Since

  [tex]E_T+E_I[/tex]

Therefore

 [tex]304.1-x=243.6[/tex]

 [tex]x=60.5kJ/mol[/tex]

Option B

Which term describes atoms with
unpaired dots in their electron dot
diagrams?

Answers

Answer:

Radicals

Explanation:

A radical refers to a chemical specie that contains unpaired electrons in their dot electron diagrams.

Radicals contain an odd number of electrons. They are commonly called odd electron species.

Radicals participate in a number of important reactions. A typical example is the halogenation of alkanes in the presence of light.

Examples of radicals include; Br. , Cl. , F. etc

The molecular formula of water is H, O. What does it express

Answers

Answer:

Firstly, the molecular formula of water would be H2O. Secondly, it expresses the amount of different atoms in the water molecule. In this case, H2 would be two Hydrogen atoms, and O would be 1 Oxygen atom.

Explanation:

Hope this helped!

Answer:

It basically means that water contains 2 atoms of Hydrogen and 1 atom of Oxygen.

It also expresses that the valency of Oxygen is 2 and water has more Hydrogen than Oxygen

characteristics of crystal​

Answers

Answer:

Crystalline solids, or crystals, have distinctive internal structures that in turn lead to distinctive flat surfaces, or faces. The faces intersect at angles that are characteristic of the substance. When exposed to x-rays, each structure also produces a distinctive pattern that can be used to identify the material.

Explanation:

Compound A has a partition coefficient (K) of 7 when comparing its solubility in CH2Cl2 to water ( K=11, [solubility of A in g/ml in CH2Cl2] divided by [solubility of A in g/ml in H2O]). If we take 17.0 g of A and partition it thoroughly between 150 ml of CH2Cl2 and 100 ml of water, what is the equation which will tell us how much of A (which is represented by x) is in the water layer after this partitioning ?

Answers

Answer:

The equation which will tell us how much of A that is mis inmthe water layer after partitioning is: 7 = (17 - x) g / 150 mL ÷ x g /100 mL

Explanation:

A partition coefficient is the ratio of the concentration of a substance in one solvent phase to the concentration in a second solvent phase when the two concentrations are at equilibrium. Usually the two phases are an organic phase and an aqueous phase. Thus, the partition coefficient K, of a compound is the ratio of the compound's concentration in the organic layer compared to the aqueous layer.

K = C₁/C₂ at equilibrium

In the compound A given, CH₂Cl₂ is the organic phase while water is the aqueous phase

Amount of A that is partitioned in between dichloromethane, CH₂Cl₂ and water, H₂O is 17.0 g

Let the amount of A that is dissolved in water be x g

Solubility of A in water given in g/mL = (x / 100) g/ml

Amount of A dissolved in dichloromethane, CH₂Cl₂ = (17 - x) g

Solubility of A in dichloromethane, CH₂Cl₂ given in g/mL = (17 - x/150) g/mL

Since the partition coefficient, K of compound A when comparing its solubility in CH₂Cl₂ to water is 7, that is;

K = [solubility of A in g/ml in CH₂Cl₂] / [solubility of A in g/ml in H2O] = 7

The equation for the amount of A in the water layer is given as follows:

7 = (17 - x) g / 150 mL ÷ x g /100 mL

Solving for x

7 = (17 -x) × 100 / 150x

7 × 150x = (17 - x) × 100

1050x = 1700 - 100x

1150x = 1700

x = 1700/1150

x = 1.48 g

How many moles of CO2 form when 4.0 mol of ethane, C2H6, react?
2C2H6 + 702 + 4CO2 + 6H20
A. 8 mol
B. 2 mol
C. 6 mol
D. 4 mol

Answers

Answer:

The amswer would be A due to the ratio between ethane and carbon dioxide being 1:2. Due to this, you double the moles that are reacting

In the following neutralization reaction, which substance is the acid?
HCI + NaOH - NaCl + H20
ОА.
НСІ
OB.
NaOH
OC.
NaCl
OD. H20

Answers

Answer:

HCl  is a acid

Explanation:

NaOH is base

Nacl is salt

Water supplies are treated with chlorine to kill pathogens. Chlorine reacts well with many other chemicals and bacterial cells because it is a strong oxidant. However, Legionella pneumophila can sometimes evade killing by residual chlorine. How does it do this

Answers

Answer:

By forming Biofilms

Explanation:

Legionella pneumophila forms biofilms by using the residual chlorine and hence act as killer of other microbial cells and intracellular pathogens.  It also colonizes within multispecies microbial communities and kills them

A steel with a critical fracture toughness of 150 MPa.m1/2 has a yield strength of 1500 MPa. If fracture were to take place at the yield stress, answer the following questions.
Surface crack size at yielding leading to failure is:_____________.
a. 0.497 cm
b. 0.994 cm
c. 0.32 cm

Answers

Answer:

c.

Explanation:

From the given information:

Critical fracture toughness [tex]K_{IC}[/tex] = 150 MPa.[tex]m ^{1/2}[/tex]

yield strength [tex]\sigma[/tex] = 1500 MPa

surface crack size [tex]a_c[/tex] = ???

The formula for the fracture toughness is can be expressed as:

[tex]K_{IC}= \sigma \sqrt{\pi a_c}[/tex]

replacing our values to solve for the surface crack size, we have:

[tex]150= 1500 \sqrt{\pi a_c}[/tex]

[tex]\dfrac{150}{ 1500} = \sqrt{\pi a_c}[/tex]

[tex]\dfrac{0.1}{1.77} = \sqrt{ a_c}[/tex]

[tex]a_c[/tex] = 0.0564²

[tex]a_c[/tex] = 0.0032 m

[tex]a_c[/tex] = 0.32 cm

how many moles of neon gas have a volume of 0.84 L and a pressure of 4.6 atm at 222k

Answers

Answer:

n = 0.21 moles

Explanation:

Given that,

Volume, V = 0.84 L

Pressure, P = 4.6 atm

T = 222 K

We need to find the number of moles of Neon gas. We know that,

PV = nRT

Where

n is the number of moles

R i the gas constant, R = 0.08206 L-atm/mol-K

Put all the values,

[tex]n=\dfrac{PV}{RT}\\\\n=\dfrac{4.6\times 0.84}{0.08206 \times 222}\\\\n=0.21\ \text{moles}[/tex]

So, there are 0.21 moles of Neon gas.

dfine chemical reaction​

Answers

Answer:

A process that involves rearrangement of the molecular or ionic structure of a substance, as opposed to a change in physical form or a nuclear reaction.

Explanation:

Pretty much just not a physical reaction or otherwise

Classification of igneous, sedimentary and metamorphic rocks is based on

A)Mineral assemblages and composition assemblages and composition

B)Appearance of the rock and texture

C)composition and mineral make-up

D)Texture and rock chemistry

Answers

It’s either( a)r (c )

Which one is the ionic compound?​

Answers

Answer:

NAF IS AN IONIC COMPOUND

Explanation:

Answer:

Explanation:

CO2 is a covalent bonding. It is something from the middle of the periodic table bonded with something on the right of the periodic table. It is not ionic.

NH3 is also covalent. The H bonds with the N and the H has properties that resemble both the metals and non metals. That's why it is on both the left and right sides of the periodic table. In this case, it is more non metallic than metallic. Since Nitrogen is on the right side of the table, you have a situation where 2 nonmetals are bonding. It is not ionic.

The answer is NaF. Sodium is on the left side of the periodic table and F is on the right side. That's what it takes to get an ionic bond.

Question 1
Consider the following reaction:
Cl2(g) + 3 F2(g) —> 2 CIF3 (8)
How many moles of product will form if 0.115 moles of fluorine gas react?

Answers

Answer:

0.077 mole of ClF₃.

Explanation:

The balanced equation for the reaction is given below:

Cl₂ + 3F₂ —> 2ClF₃

From the balanced equation above,

3 moles of F₂ reacted to produce 2 moles of ClF₃.

Finally, we shall determine the number of mole of ClF₃ produced by the reaction of 0.115 mole of F₂. This can be obtained as follow:

From the balanced equation above,

3 moles of F₂ reacted to produce 2 moles of ClF₃.

Therefore, 0.115 mole of F₂ will react to to produce = (0.115 × 2)/3 = 0.077 mole of ClF₃.

Thus, 0.077 mole of ClF₃ was obtained from the reaction.

No tires P ni basura al suelo

Answers

Answer:

no halbo ingles

Explanation:

What is the major organic product obtained from the sequence of reactions 2-phenyl-4 bomobutane and NaN3?

Answers

Answer:

(E)-1-phenylbut-1-ene

Explanation:

2-phenyl-4 bromobutane is an amphetamine that contains a phenyl group. It forms a major stable product with other reacting agents.

The major organic product that is obtained from the sequence of the reactions of the 2-phenyl-4 bomobutane when it reacts with [tex]NaN_3[/tex] is the (E)-1-phenylbut-1-ene.

Thus the answer is 2-phenyl-4 bromobutane is an amphetamine that contains a phenyl group. It forms a major stable product with other reacting agents.

The major organic product that is (E)-1-phenylbut-1-ene.


2 AICI3 + 3 Ca - 3 CaCl2 + 2 Al
You react aluminum chloride with calcium metal. You want to produce 40.00 grams of aluminum. How many grams of calcium do you need?

Answers

50 grams of calcium

If 7.90 mol of C5H12 reacts with excess O2, how many moles of CO2 will be produced by the following combustion reaction?

C5H12+8O2=6H2O+5CO2

Answers

Answer:

moles CO₂ produced from combustion of 7.9 mole of C₅H₁₂ = 39.5 moles CO₂

Explanation:

              C₅H₁₂      +   8O₂      =>      6H₂O      +      5CO₂

Given:   7.9moles    excess            _____            ? moles

             

From Equation, 1 mole C₅H₁₂ =============>  5 moles CO₂

Given            7.9 mole C₅H₁₂  =============>         X

Solving for 'X' using ratio and proportion ...

1mole C₅H₁₂ / 7.9mole C₅H₁₂ =  5mole CO₂ / X

=> X = 5 mole CO₂ x  7.9mole C₅H₁₂ / 1mole C₅H₁₂  =  39.5 moles CO₂

≅ 40 moles CO₂ (2 sig. figs.)

Which of the following reasons explains why if salt water is heated, the water turns into steam while the salt remains?

Water and salt have an equal boiling point.
Water has a lower boiling point than salt.
Salt has a lower boiling point than water.
Salt and water have an equal melting point.

Answers

If the salt water is heated, the water turns into steam and the salt remains because the water has a lower boiling point than the salt.

The  following points can be considered:

The boiling point is defined as the temperature at which the substance turns into the gaseous state from the liquid state.The boiling point of water is [tex]100^{o} C[/tex].The salt is a substance comprising two entities separated by the opposite charges with ionic interactions.The boiling point of a salt is higher than the boiling point of the water.

The process involved when salt water is heated:

The salt water mixture when heated, the water turns into steam at [tex]100^{o} C[/tex]But the salt remains until it reaches its boiling temperature. If the salt is soluble in water and is then heated, then there occurs an elevation in the boiling point of the substance, due to the presence of the salt.

Therefore, the answer is water has a lower boiling point than salt.

Learn more about salt:

https://brainly.com/questions/4076105

Match each term with the best description.

a. The electrode where oxidation occurs
b. A device that produces electricity
c. The connection between two half-cells
d. The electrode where reduction occurs
e. A device that consumes electricity
f. A device that utilizes redox reactions to either consume or produce electricity

1. Anode
2. Cathode
3. Electrolytic cell
4. Electrochemical
5. Galvanic cell
6. Salt bridge

Answers

Answer:

Match each term with the best description.

a. The electrode where oxidation occurs: Anode

b. A device that produces electricity: Galvanic cell

c. The connection between two half-cells: salt bridge

d. The electrode where reduction occurs: Cathode

e. A device that consumes electricity: Electrolytic cell

f. A device that utilizes redox reactions to either consume or produce electricity: Electrochemical cell.

Explanation:

a.The electrode where oxidation occurs is called the anode.

Oxidation is losing of electrons.

b. Galvanic cell produces electricity by using redox chemical reaction.

It is also called a voltaic cell or electrochemical cell.

c. The connection between two cells is called a salt bridge.

It will not allow the solutions to diffuse with each other.

It maintains electrical neutrality.

d. The electrode where reduction occurs: Cathode

Reduction means the gaining of electrons.

e. Electrolytic cell is the one that consumes electricity and then produces a chemical change.

f. A device that utilizes redox reactions to either consume or produce electricity: Electrochemical cell.

Write the bond line formula for the compound (CH3)2CHCH2C(CH3)3.​

Answers

Formula is (CH3)2CHCH2C(CH3)3 and the name is 2,2,4-trimethylpentane

The specific heat capacity of liquid water is 4.18 J/g-K. How many joules of heat are needed to raise the temperature of 6.00 g of water from 36.0°C to 75.0 °C?

Answers

Answer:

978 J

General Formulas and Concepts:

Thermodynamics

Specific Heat Formula: q = mcΔT

q is heat (in J) m is mass (in g) c is specific heat (in J/g °C) ΔT is change in temperature (in °C)

Explanation:

Step 1: Define

[Given] c = 4.18 J/g K

[Given] m = 6.00 g

[Given] ΔT = 75.0 °C - 36.0 °C = 39.0 °C

[Solve] q

Step 2: Find q

Substitute in variables [Specific Heat Formula]:                                             q = (6.00 g)(4.18 J/g K)(39.0 °C)Multiply [Cancel out units]:                                                                              q = 978.12 J

Step 3: Check

Follow sig fig rules and round. We are given 3 sig figs.

978.12 J ≈ 978 J

Answer:

I don't remember this topic very well.

Explanation:

if we want to increase 1C° of 1 gram water. we must use 4.18 joules energy that 75-36= 39 C° for 6 gram H2O we should use 6*39*(4.18) joules

4. An exothermic reaction is accompanied by a decrease in entropy. How would this reaction be
classified?
A. spontaneous at all temperatures
B. nonspontaneous only at low temperatures
C. nonspontaneous at all temperatures
D. spontaneous only at low temperatures

Answers

Answer:

Spontaneous at only low temperature. I made a chart for my AP Chem class if you want to refer to it.

A student calculates the empirical formula of a compound to be C1.5H3.5. Express this as a correct empirical formula.

Answers

Answer:

No, the correct empirical formula is [tex]C_3H_7[/tex].

Explanation:

Hello there!

In this case, according to the given information, it turns out necessary for us to bear to mind the fact that empirical formulas must not be expressed in decimal numbers, for that reason, we need to multiply the given empirical formula by 2 to get the correct one:

[tex]C_3H_7[/tex]

Which is now possible.

Regards!

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