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In an experiment hydrochloric acid is added drop by drop to solid sodium sulfite (Na2SO3). A gas is evolved and collected. Half of the collected gas is added to Lugol solution (I2 dissolved in KI solution), the other half of the gas is added to hydrogen sulfide solution. Write the equation of the reactions, discuss the observations that can be seen during the reactions and explain the changes. In your answer, also discuss the followings:


a) What gas is liberated during the reaction between HCl and Na2SO3? Why can it be liberated this way? Write an equation for the reaction.


b) What ability of the gas is
demonstrated in the reactions with Lugol solution and with H2S? Write equations and use oxidation numbers to prove it. What makes it possible for the substance to act differently in the two reactions?


c) What other properties of the gas evolved can you recall?


d) What are the environmental implications of the gas evolved? Write the appropriate equation for the reaction.

Answers

Answer 1

SO2 acts both as an oxidizing and a reducing agent depending on the conditions of the reaction. It also leads to acid rain.

The reaction of HCl with Na2SO3 occurs as follows;

Na2SO3 + 2HCl ------> 2NaCl + SO2 + H2O

The gas evolved in the reaction is SO2. It is liberated because sulfites react with acids to liberate sulfur IV oxide.

The ionic equation of the reaction is; [tex]SO3^2-(aq) + 2H^+(aq) ----> SO2(g) + H2O(l)[/tex]

The reaction of SO2 with Lugol solution occurs as follows;

SO2 +I2 + 2H20→ H2SO4 + 2HI. This demonstrates oxidation because sulfur is oxidized from +4 to +6 state from left to right. This shows SO2 as a reducing agent.

With H2S, the gas reacts as follows;

2H2S + SO2 → 3S (s) + 2H2O

The oxidation number of sulfur decreases from +4 to zero. This demonstrates the gas as an oxidizing agent. SO2 can act as oxidizing or reducing agent because it can change its oxidation state to +6(oxidation) by electron loss or gain electrons to decrease its oxidation state as low as -2.

The gas SO2 is an acid gas. It dissolves in water to yield an acid solution. Also SO2 is a bleaching agent. The major environmental impact of SO2 is that it leads to acid rain as follows; 2SO2 + O2 + 2H2O⇌2H2SO4.

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Related Questions

Which which characteristics determines color? A. The Measurement from crest crest. B. The highest point on the wave. C. The lowest points on the waves D. The number of waves that pass per second. Please give me a good response.

Answers

Answer:

The answer is option A

Explanation:

This is because the measure from crest to crest is also known as the wavelength, and the color of a wave always depends on its wavelength, if you see the electromagnetic spectrum

Hope this helps!

The answer is ‘A’ because the measure from crest to crest is also called the wavelength. The color of the wavelength depends on its wavelength ,if you see the electromagnetic spectrum:))

‏The result of a division problem is the a ) divisor . b ) quotient . c ) factor . d ) remainder .

Answers

Answer:

The number by which we divide is called the divisor. The result obtained is called the quotient. The number left over is called the remainder.

Explanation:

The boiling point of a substance is tested. After 10 tests, the result is given as 37+/−3°C. Which conclusion can be drawn from this result?

A- The scientists do not need to collect more data because they have narrowed down the range of the results.

B- The scientists should not report these results until they have the exact number.

C- The actual boiling point is either 34°C or 40°C.

D- The actual boiling point is probably between 34°C and 40°C.

Answers

From the data obtained from the tests, the actual boiling point lies between 34°C and 40°C.

The boiling point of a substance is the temperature at which the pressure of the substance becomes equal to atmospheric pressure. Pure substances have a sharp boiling point while impure substances boil over a temperature range.

In this case, the boiling point of the substance after 10 tests is obtained as 37+/−3°C. This implies that the actual boiling point lies between 34°C and 40°C.

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Grace wanted to find out the best conditions for growing lettuce plants.
She took 4 trays and planted 8 lettuce plants in each.
The results of her investigation are shown below.

How many days did the investigation last?
Use the table to help you.

Answers

Explanation:

the investigation lasts for 7 days !

hope this helps you.

The box shows the chemical formula for bleach.

Answers

Bleach contains sodium chlorine and oxygen

he hybridization of carbon in diamond is _________. Enter your answer with no superscripts or subscripts, i.e., ab3.

Answers

Diamond is composed of hexagonal rings in which sp3 hybridized carbon atoms are linked together.

Hybridization refers to the mixing of atomic orbitals to yield hybrid orbitals that are suitable for bonding. The energy of orbitals that combine to form hybrid orbitals must be close enough for such combination to take place.

Diamond is composed of hexagonal rings in which sp3 hbridized carbon atoms are linked together. Each carbon atom in diamond is tetrahedral.

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The mixing of the two different orbitals to form a compound is called hybridization. For example mixing of s and p orbits.

The correct answer is sp3.

The arrangement of the elements in a different manner to form a new compound is called allotropes. For example, diamond and graphite are the allotropes of carbon.

The valence electrons are in p orbitals and p orbit mixed after the s orbitals.

Therefore, the correct answer is sp3

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An element with 5 valence electrons would be a
0 - 3 anion
O +5 anion
0-5 cation
O + 3 cation

Answers

Answer:

ask you subject teacher

Explanation:

Commercially prepared cloning vectors such as pUC18 are designed to contain several useful features. An example of one of these features is ________.

Answers

Vectors may be plasmids. An example of one of several useful features of commercially prepared cloning vectors is MULTIPLE CLONING SITES.

The pUC18 vector is a widely used standardized cloning vector for replication in Escherichia coli.

A multiple cloning site can be defined as a short DNA fragment observed in genetically engineered plasmids.

These DNA fragments (multiple cloning sites) contain twenty (20) or more sites where restriction enzymes can cut in order to generate recombinant DNA molecules.

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How many carbon dioxide molecules and water molecules are needed to make one molecule of glucose?

Answers

Answer:

It takes six molecules of carbon dioxide and six molecules of water to make one molecule of glucose.

What mass of aluminium chloride can be obtained when 0.48mols of aluminium is completely reacted with dilute hydrochloric acid?
Equation for this reaction:
2Al + 6HCl 2AlCl3 + 3H2​

Answers

Answer:

Explanation:

we will do ratio method

Aluminum chloride :  Aluminum

2                               :      2

0.48                          :      x

(cross multiply)

0.48 x 2 / 2 = 0.48 moles of aluminum  

mass = 1 mole of aluminum chloride x moles

mass = 133.33 x 0.48

mass = 63.9984g (round off) = 64g

I hope this helps.

Explain how you determine the freezing point of a solution that does not have a well-defined transition in the cooling curve.

Answers

This question is asking for a method for the determination of the freezing point in a solution that does not have a noticeable transition in the cooling curve, which is basically based on a linear fit method.

The first step, would be to understand that when the transition is well-defined as the one on the attached file, we can just identify the temperature by just reading the value on the graph, at the time the slope has a pronounced change. For instance, on the attached, the transition occurs after about 43 seconds and the freezing point will be about 4 °C.

However, when we cannot identify a pronounced change in the slope, it will be necessary to use a linear fit method (such as minimum squares) to figure out the equation for each segmented line having a significantly different slope and then equal them so that we can numerically solve for the intercept.

As an example, imagine two of the segmented lines have the following equations after applying the linear fit method:

[tex]y=-3.5 x + 25\\\\y=-0.52 x + 2[/tex]

First of all, we equal them to find the x-value, in this case the time at which the freezing point takes place:

[tex]-3.5 x + 25=-0.52 x + 2\\\\-3.5 x+0.52 x =2-25\\\\x=\frac{-23}{-2.98}=7.72[/tex]

Next, we plug it in in any of the trendlines to obtain the freezing point as the y-value:

[tex]y=-3.5 (7.72) + 25\\\\y = 1.84[/tex]

This means the freezing point takes place after 7.72 second of cooling and is about 1.84 °C. Now you can replicate it for any not well-defined cooling curve.

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How many double bonds does CCL2H2 have?

Answers

None. Both chlorines and both hydrogens are single-bonded to the central carbon atom; the molecule is comprised of four single bonds and no double bonds.

Hope this helps!

Jackson uses a battery operated toothbrush that is rechargeable. what happens when Jackson plugs in his toothbrush into an electrical outlet to recharge it ?

A. chemical energy is transformed to sound energy.
B. electrical energy is transformed to kinetic energy.
C. chemical energy is transformed to kinetic energy.
D. electrical energy is transformed to chemical energy​

Answers

Answer:

the answer would be B

Explanation:

The power from the charger use electricity and the electricity transforms to energy that can be moved

If 5 g of sodium chloride saturates 12.5 g of water at 10 °C, what mass of sodium chloride would saturate 50 g of water at constant temperature? ​

Answers

Explanation:

since 5g saturates 12.5g of water at 10°c

so......x would saturate 50g of water at 0°c

then you can cross multiply

Suppose you have samples of three unknown solids. Explain how you could use their properties to
determine whether or not they are ionic solids.

Answers

Using melting and boiling temperature, hardness and electric current passing testing.

Ionic solids

Ionic solids are materials that have a strong bond between their ions, thus producing well-defined shapes.

In addition, due to this strong attraction, the boiling and melting temperatures of these materials are very high, in addition to the resistance to breakage presented by them.

Finally, ionic solids are also excellent conductors of electricity.

So, their properties used to determine whether or not they are ionic solids are  melting and boiling temperature, hardness and electric current passing testing.

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Draw the other possible resonance structure of each organic ion. In each case, draw the structure that minimizes formal charges. Be sure to include all appropriate nonbonding electrons and charges. A three carbon chain with a double bond between carbons 1 and 2. Carbon 1 is bonded to two hydrogen atoms, carbon two is bonded to one hydrogen atom, and carbon three is bonded to two hydrogen atoms. There is a plus one charge on the third carbon atom. Draw the resonance structure of the allyl ion. A carbon atom is single bonded to a C H 3 group, double bonded to an oxygen atom, and single bonded to an N atom. The N atom is bonded to a hydrogen atom. It has two lone pairs and a minus one charge. The O atom has two lone pairs. Draw the resonance structure of the amidate ion.

Answers

Three resonance structures  can be drawn for the allyl cation while two resonance structures can be drawn for the amidate ion.

Sometimes, we cannot fully describe the bonding in a chemical specie using a single chemical structure. In such cases, we have to use a number of structures which cooperatively represent the actual bonding in the molecule. These structures are called resonance or canonical structures.

The resonance structures of the allyl cation and the amidate ion are shown in the images attached to this answer. These structures show the different bonding extremes in these organic ions.

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2. Why do you think electroplated jewelleries are in demand?
Chemistry plsss

Answers

Explanation:

Electroplated jeweleries are in demand because firstly they are as shiny and attractive as real jeweleries, they are also light weighted and cost effective.

Al2(SO3)3
a. Count the number of Sulfur atom
b. How many total atoms are given in the compound
Please helppp

Answers

Answer:

from the words below underline six example of rhetorical patterns

Oil does not dissolve in water because

Answers

Explanation:

Oils are made up of long hydrocarbon chains which are non polar. Since water is a polar solvent oil doesn't dissolve in water well.( Polar solutes dissolve in polar solvents and non polar solutes dissolve in non polar solvents) The hydrocarbon chains are hydrophobic.

Sodium hydroxide neutralises hydrochloric acid as shown in the equation:
NaOH(aq) + HCl(aq) i NaCl(aq) + H2O(l)
(4)
dm3
(3)
The student found that 27.20 cm3 of 0.100 moles per dm3 sodium hydroxide neutralised 5.00 cm3 of hydrochloric acid.
Calculate the concentration of the hydrochloric acid in moles per dm3.
Give your answer to three significant figures.

Answers

Explanation:

Mole ratio of NaOH : HCl = 1: 1

Moles of NaOH used = 0.1 mol/1000 cm3 × 27.20 cm3

= 2.72 × 10^-3 mol

Therefore moles of HCl used is also 2.72 × 10^-3 mol

So concentration of HCl can be found by dividing the no.of moles of HCl by the volume of HCl as follows

2.72 × 10^-3 mol/ 5cm3

1000cm3 = 1dm3

Therefore,

1cm3 = 1/1000 dm3

5cm3 = 5/1000 dm3

HCl conc. = 2.72 × 10^-3 mol/ 5×10^-3 dm3

= 0.544 moldm-3

what did mosa figure out? how did mosas mesurement prove that the ball was moving to gravity

Answers

by bouncing it

Explanation:

when you bouce a ball it hits the ground because gravity pulls it down

Hello can someone please help me. Me and my mom went to the doctor and the doctor told me I can’t have sex till 19 because of my health problems. But they didn’t tell me what health problems! Can someone tell us there any health things or a name for that?

Answers

Answer:

bladder or bowel diseases, or arthritis. These might be your answer.

A balloon with an initial volume of 3.1 L at a temperature of 193 K is warmed to 374 K.

What is its volume at the final temperature? (Assume constant temperature.)

Answers

Answer:

New volume = 6.0L

Explanation:

Make a list of variables given in the question, and what we want to find:

Initial volume (L) = Vi = 3.1

Initial temperature (K) = Ti = 193

New temperature (K) = Tn = 374

New volume (L) = Vn

We have volumes and temperatures given and we're talking about gas, the equation including both these variables that should come to mind is the ideal gas equation:

PV = nRT

P = pressure (Pa)

n = number of moles

R = gas constant = 8.31

Now, we construct an equation we can solve to get the new volume:

P(Vn) = nR(Tn)

And insert the values we know:

P(Vn) = n(8.31)(374)

P(Vn) = n·3107.94

The equation contains 3 unknown variables;

We should first try to see if we can eliminate the 2 we are not interested in, namely P and n;

What we should recognise is that the pressure and number of moles will not change upon warming the balloon;

Firstly, heating the gas inside the balloon doesn't add anything to the balloon, i.e. doesn't increase the moles of gas, it simply raises the energy of the gas particles already within the balloon, so n will not change;

Secondly, I think there is a mistake in the question, it should read "assume constant pressure" in the brackets, since the temperature does change, which we are told;

Also, we can assume normal atmospheric pressure inside and outside the balloon as would be the case ordinarily;

What we want to do with this information is rearrange the equation we constructed to have these 2 constant or unchanging variables on one side and everything else on the other, so:

[tex]\frac{P}{n} = \frac{3107.94}{V_{n} }[/tex]

Next, we construct an equation for the balloon before warming:

P(Vi) = nR(Ti)

P(3.1) = n(8.31)(193)

P·3.1 = n·1603.83

Once again, rearrange to get P and n on one side of the equation and everything else on the other:

[tex]\frac{P}{n} = \frac{1603.83}{3.1} \\\\ \frac{P}{n} = 517.364516[/tex]

Now, we have two equations for P/n, we can eliminate P/n since both these values remain the same before and after warming the balloon as previously established:

[tex]\frac{3107.94}{V_{n} } = \frac{P}{n} = 517.364516 \\\\ \frac{3107.94}{V_{n} } = 517.364516 \\\\[/tex]

Now, rearrange and solve for Vn:

[tex]\frac{3107.94}{V_{n} } = 517.364516 \\\\ V_{n} = \frac{3107.94}{517.364516} \\\\ V_{n} = 6.00725...[/tex]

Vn = 6.0L

Calculate the Ka of your acetic acid solution. Discuss this calculation. Based on the value of Ka, is acetic acid a strong acid or a weak acid

Answers

Based on our knowledge of strong and weak acids, we can confirm that the Ka value for acetic acid will be relatively low since it is a weak acid.

Acids can be strong or weak. This is determined by its tendency to break apart into ions or stay together to form molecules. Although somewhat counter-intuitive, strong acids are those that are most likely to break apart and therefore contain a high number of ions within their solutions.

Weak acids, on the other hand, are those that tend to stay together in the form of molecules and therefore possess very low ion counts in their solutions. The acid dissociation constant, Kₐ, is used to measure whether an acid is weak or strong and how much so. In the case of Acetic acid, the ka measurement will offer a low value, indicating a weak acid.

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One night a student notices that one-quarter of the moon is visible. What is the likely explanation for this view?

Answers

If a student notices that  one-quarter of the moon is visible, a lunar eclipse has taken place.

Eclipse is said to occur when one of the heavenly bodies casts a shadow on another heavenly body causing it to be partly visible or completely invisible. When the earth comes between the sun and the moon, a lunar eclipse is said to occur.

When a lunar eclipse occurs, the moon may be partly visible or completely invisible. Therefore, if a student notices that  one-quarter of the moon is visible, a lunar eclipse has taken place.

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if you are a scientific or a inventor what do you want to discover or to invent relate to electrogmagnetism​

Answers

Answer:

Michal Faraday 19th century

The table shows the order of the Sun and some of the planets in our solar system.
The letters represent the Earth, Neptune and the Sun, so match them up in your answer.

Answers

Explanation:

A=Sun

B=Earth

C=Neptune.

hope my answer will definitely help you out.

A chemical property is a change in _____.

density

physical state

hardness

composition of matter

Answers

Answer:

composition of an element

The melting point of H₂O(s) is 0 °C. Would you expect the melting point of H₂S(s) to be 85 °C, 0 °C or -85 °C.? Justify your choice

Answers

Answer:

-85 °C

Explanation:

O and S are in the same group( Group 16). Since S is below O it's atomic mass is higher than O. So molar mass of H2S is higher than H2O. The strength of Vanderwaal Interactions ( London dispersion forces) increases when the molar mass increases. However, only H2O can form H bonds with each other. This is because electronegativity of O is higher than S and therefore H in H2O has a higher partial positive charge than H of H2S.

H bond dominate among these 2 types of forces so the strength of attractions between molecules is higher in H2O than H2S. Therefore more energy should be supplied for H2O to break inter

molecular forces and convert from solid to liquid state than H2S. So mpt of H2O must be higher than that of H2S.

Describe your observations when the paper clip was gently crushed with the pestle

Answers

Answer:

We can do an experiment with vinegar to see what happens to the calcium in an eggshell when it is exposed to an acid.

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