Potassium chlorate, a common oxidizing agent in fireworks and matchheads, undergoes a solid-state disproportionation reaction when heated:

4KClO3 (s) ⟶ Δ3KClO4 (s) + KCl (s).

Use ΔHf ° and S° values to calculate ΔG_sys ° (which is ΔGrxn °) in kJ at 25°C for this reaction.

Answers

Answer 1

Answer:

Explanation:

[tex]\text{From the information given:}[/tex]

[tex]\text{The chemical reaction is : } 4 KClO_{3(s)} \to 3 KClO_{4(s)} + KCl_{(s)}[/tex]

[tex]\text{To find} \ \Delta G^0_{rxn}\ \text{using the formula}: \\ \\ \Delta G^0_{rxn} = \sum n_p \times \Delta _f G^0 (Products) - \sum n_R \times \Delta _fG^0 ( Reactants) \\ \\ where; n_p = \text{no of moles of products } \ and; \\ \\ n_R = \text{no of moles of reactants }[/tex]

[tex]\implies G^0_{rxn} = 3 \times \Delta _fG^0 [KClO_4{(s)}] + \Delta_fG^0[KCl_{(s)}] - 4 \times \Delta _f G^0 [ KClO_3 (s) ][/tex]

[tex]\Delta _fG^0 \ values \ at \ 25^0 \ C (298 \ K) are\ given \ as:\\\\ \Delta _fG^0 [KClO_4(s)] = -303.09 \ kJ \\ \\ \Delta _fG^0 [KCl(s) ] = - 409.14 \ kJ \\ \\ \Delta_f G^0 [KClO_3_{(s)}] = -296.25 \ kJ \\ \\ replacing \ the \ above \ values \ into \ equation (1) ; then:\\ \\ \\\Delta G^0_{rxn} = 3 *(-303.09) + (-409.14) - 4*(-296.25) \ kJ \\ \\ = (-909.27 - 409.14 + 1185) \ kJ \\ \\ = -133.41 \ kJ \\ \\ \mathbf{\Delta G^0_{rxn} = -133.4 \ kJ }[/tex]

Answer 2

The standard free energy change of the reaction is -133 kJ.

From the reaction equation, we have; 4KClO3 ⇄ 3KClO4 (s) + KCl (s). The standard free energy of formation of each specie is given below;

ΔG°f KClO3 = -296.35 kJ

ΔG°f KClO4 = -303.09 kJ

ΔG°f KCl = -409.14 kJ

Hence;

ΔG°rxn = [3(-303.09)] + ( -409.14)] - [(4( -296.35))]

ΔG°rxn = (-909.27) + (-409.14) - (-1185.4)

ΔG°rxn = -133 kJ

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Related Questions

Express these temperatures in degrees Fahrenheit and in kelvins. A.-252.97 C B. -40 C C. 1,064 C

Answers

Answer:

A. -423.346 °F, 20.18 K

B. -40°F, 233.15K

C. 1947.2 °F, 1337.15 K

Explanation:

A.

(-252.97 °C × 9/5) + 32 = -423.346 °F

-252.97 °C + 273.15 = 20.18 K

B.

(-40 °C × 9/5) +32 = -40 °F

-40 °C + 273.15 = 233.15 K

C.

(1064 °C ×9/5) + 32 = 1947.2 °F

1064 °C + 273.15 = 1337.15 K

There are eight diastereomers of 1,2,3,4,5,6-hexachlorocyclohexane. One of them is drawn. Draw the other seven in the cyclohexane framework below (5 points). One isomer loses HCl in an E2 reaction nearly 1000 times more slowly than the others. Circle the isomer that reacts so slowly, draw its corresponding chair conformers and explain the reason for the slow rate. (5 points).

Answers

Answer:

Attached below diagram of the eight diastereomers

The Isomer that reacts so slowly is DIASTEREOMER 8

Explanation:

The Isomer that reacts so slowly is DIASTEREOMER 8 in an E2 reaction and this is because no pair of chlorine and hydrogen atoms can assume the anti-periplanar orientation that is preferred in an E2 elimination

attached below is Diagram of the eight diastereomers ( screen shot from my drawing tool )

Which Video game do you like the most?
Minecraft
Roblux because it won't allow me to say the actually game name
Fortnut same for this one
Call of duty
grand theft auto
Red redemption and
Geometry dash

Answers

minecraft or cod

Explanation:

well those are the only games I play but the one I enjoy the most is cod

GD

cnm nmvnvjngggguhygtcdffgvbhnmi

A compound accepts electrons from another substance to form a covalent bond. Which term best describes this
compound's behavior?
-Lewis acid
-Arrhenius base
-Bronsted-Lowry acid
-Bronsted-Lowry base

Answers

Answer:

A). Lewis Acid

Explanation:

deez

The term that best describes the compound that accepts electrons from another substance to form a covalent bond is Lewis acid.

What is Lewis acid?

Lewis acid is a compound or ionic species which can accept an electron pair from a donor compound while a Lewis base is a compound such as the OH- ion, that can donate a pair of non-bonding electrons.

According to this question, a compound accepts electrons from another substance to form a covalent bond.

Therefore, the term that best describes the compound that accepts electrons from another substance to form a covalent bond is Lewis acid.

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7. Gasoline is a nonpolar liquid that will float on water. 450 grams of gasoline is spilled into a puddle of water. If the
density of gasoline is 0.665 g/mL, what volume of gasoline is spilled?

Answers

Just unit conversions here. 450 g / 0.665 g/mL ≈ 677 mL of gasoline

The area covered by the matter is called volumes. Each matter has its own volume and surface area.

The correct answer to the question is 677ml of gasoline.

The formula is used for the question is as follows:-

[tex]M = D*V[/tex]

All the data given in the question is as follows:-

M is 450gD is 0.665

After putting in the equation, the volume we get is as follows:-

[tex]\frac{450 g }{0.665} = 677mL \ of\ gasoline[/tex]

Hence 677 ml is the volume.

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which answer? Is this

Answers

Answer:

law of segregation

have a good day!

Explanation:

Calculate the mass of CO2 that can be produced if the reaction of 54.0 g of propane and sufficient oxygen has a 64.0% yield.

Answers

Answer:

103.9 g

Explanation:

C₃H₈ + 5O₂ → 3CO₂ + 4H₂O

First we convert 54.0 g of propane (C₃H₈) into moles, using its molar mass:

54.0 g ÷ 44 g/mol = 1.23 mol C₃H₈

Then we convert 1.23 moles of C₃H₈ into moles of CO₂, using the stoichiometric coefficients:

1.23 mol C₃H₈ * [tex]\frac{3molCO_2}{1molC_3H_8}[/tex] = 3.69 mol CO₂

We convert 3.69 moles of CO₂ into grams, using its molar mass:

3.69 mol CO₂ * 44 g/mol = 162.36 g

And apply the given yield:

162.36 g * 64.0/100 = 103.9 g

Definition of Acid, base and
salt​

Answers

Answer:

nenrhj4rhty4bdwkwwa

Explanation:

At which point in its swing does the pendulum have the least gravitational potential energy

Answers

Answer:

a

Explanation:

a

Identify the type of reaction.

Al + MgSO4 = Al2(SO4)3 + Mg

Answers

Answer: its combustion

Explanation:

What are the differences between an atom, a molecule, and a compound?

Answers

Answer:

Atoms are the thing that make up molecules and compounds. Molecules contain two or more atoms and are held together by covalent bonds, whereas compounds are held together by ionic bonds. Two or more elements bonded together through ionic attraction.

Explanation:

Atoms are the thing that make up molecules and compounds. Molecules contain two or more atoms and are held together by covalent bonds, whereas compounds are held together by ionic bonds.

How many Protons, Electrons and Neutrons does Helium-6 have?

Answers

Answer:

12 neutrons

2 protons

2 electrons

Answer:

Hello There!!

Explanation:

Helium 6 has:

-two protons

-two electrons

-two neutrons

hope this helps,have a great day!!

~Pinky~

The reason for the trend in the previous question is because Bromine is _________electron density from the carbon the proton is on, resulting in the proton being ___________, thus the proton nuclei is_________ effected by the applied magnetic field leading to a greater difference in energy of the nuclei's spin states.

Answers

Answer:

Explanation:

From this question, we are to fill in the blanks with the appropriate correct answers.

[tex]\text{The reason for the trend in the previous question is because Bromine is } \mathbf{withdrawing}[/tex][tex]\text{electron density from the carbon the proton is on, resulting in the proton being }\mathbf{deshielded, }[/tex][tex]\text{thus the proton nuclei is} \ \ \mathbf{more} \ \ \text{effected by the applied magnetic field leading to a }[/tex]

[tex]\text{greater difference in energy of the nuclei's spin states.}[/tex]

NOTE: that the electron-withdrawing groups decrease the electron density around the proton nucleus and therefore the nucleus feels the external magnetic field more. Hence, it requires a larger frequency to attain resonance(downfield).

5,6-dimethyl-2-heptyne

Due in 1 hr pls help me

Answers

Answer:

Please see the attached pictures.

Explanation:

☆ To ensure that each carbon has 4 bonds, fill the other bonds with Hs.

what career field/job would utilize ppm units
A environmental jobs
B Medical fields
C Jobs at the brewery
D Jobs in analytical chemistry

Answers

Jobs in analytical chem tht is because it’s parts per million and when calculating the amount of an element in a mole

What observations and reasoning led to the development of Hubble's Law?

Answers

Answer:

Hubble's law says that the universe is expanding outward.

Explanation:

Actually Hubble's law was discovered before the Big Bang theory was formulated. The Big Bang Theory is an attempt to explain the observations that led to Hubble's Law.Before the 1900s the theory was that the universe was eternal and self existent. The idea was that the universe was in a steady state having always existed and would always continue to exist. Albert Einstein even changed the equations in his general theory of relativity to reflect the idea of a steady state. Later he called putting in a fudge factor to result in a steady state the worse mistake of his life.

Hubble observed that most of the universe has a red shift indicating that the universe is expanding and moving away from itself. The further out that the universe is observed the faster it is moving apart.

These observations were inconsistent with a steady state universe.

The Big Bang theory extrapolated backwards. If the universe is expanding and spreading out from itself then further back in time the universe was closer together. The Theory explained Hubble's observations by the idea that at the beginning of time ( for our universe) all the matter and energy were together in one place.

This super dense ball of matter and energy then exploded outwards creating space and time as it is presently observed. The question was would the forces of gravity and black holes bring the matter and energy back together again. The answer found in 1998 was no. The rate of the expansion of the universe is increasing not slowing down and the universe will not collapse back into the super dense ball of matter that it began as.

The Big Bang Theory postulated based on the empirical evidence that our universe had a beginning and it will eventually cease to exist. The conclusion based on Hubble's observations is that matter and energy are not eternal and self existent.

Give an example of an electrolyte ​

Answers

Answer: sodium chloride water solution

Explanation: Eelctrolyte contains cations and anions which can

Transfer charge

Answer:

some energy drinks like powerade or Gatorade, and some juice drinks to.

A scientist places 10 ml of water in a test tube and heat it with flaming burner for 2 minutes. The liquid boils and escapes as a steam. This experiment is a good example of a

A chemical change

B physical change

C chemical property

D physical property​

Answers

physical change

the easiest way to tell between is a chemical or physical change, is when you ask yourself this: did the substance change?
in this scenario, water and steam are still considered the same thing. they’re both different forms of water. if something in a reaction stays the same substance, it’s a physical change.

If 22.4L = I moles How many liter of CO2 are produced if you produce 9.6 moles of CO2?

Answers

Answer:

215 moles

Explanation:

[tex]9.6mol CO_{2} (\frac{22.4 L CO_{2}}{1 mol CO_{2}} ) = 215 L CO_{2}[/tex]

The action of a tree stump splitting bedrock depicts what type of process?

А. chemical weathering

B. physical weathering

С. deposition

D. erosion

Answers

B. Physical weathering

Answer: Physical Weathering

Explanation: It is physical weathering because it is caused by natural elements causing the rock to break. It is not chemical weathering because it is not using any chemical reaction to break the rock. It is not erosion or deposition because it is still not finished with the process with breaking the rock. Think of it this way:

Step 1: Weathering - Breaks rock/stone

Step 2: Erosion - Taking the small bits of rock

Step 3: Deposition - Dropping the rock

what is the difference between potential energy and kinetic energy?

A. potential energy is the energy of an object due to its position while kinetic energy is energy due to its motion
B. potential energy is the energy of an object due to its motion while kinetic energy is energy due to its position
C. potential energy is the energy of an object due to the applied Force while kinetic energy is energy stored after the applied force.
D. potential energy is the energy stored after an applied force while kinetic energy is the energy used from the applied force​

Answers

Answer:

A

Explanation:

Potential energy is stored energy. Kinetic energy is energy of motion.

What is the hydrogen ion concentration ([H']) of a substance with a pH of 4.91?

Answers

Answer:

The pH of a solution is a measure of the concentration of hydrogen ions in the solution. A solution with a high number of hydrogen ions is acidic and has a low pH value. A solution with a high number of hydroxide ions is basic and has a high pH value. The pH scale ranges from 0 to 14, with a pH of 7 being neutral.

When we report the concentration of a solution we are using the moles of the entire compound.

a. True
b. False

Answers

Answer:

b. False

Explanation:

The formula to find the concentration of a solution is we simply divide the number of moles of the solute with total solution volume in liters. This gives the molar concentration of a solution. Clearly we do not use the number of moles of the entire compound but only that of solute.

Hence, we can conclude that the given statement is false.

In this field of sunflowers variation exists some flowers are tall others short

Answers

Answer:

Some flowers are tall, others short, and finally some plants are an intermediate height. The tallest plants shade the shorter; the taller plants are

Explanation:

five good habit to clean our surrounding​

Answers

Answer:

Explanation:

Invest in a reusable water bottle. ...

Bring your own reusable cup. ...

Refuse single-use items. ...

Avoid products with microbeads. ...

Shop in bulk

Pick up trash you see

Reuse water bottles

Car pool if ur friends go to the same place

Plain trees

Walk and not drive if where ur going is close

When a lead acid car battery is recharged by the alternator, it acts essentially as an electrolytic cell in which solid lead(II) sulfate PbSO4 is reduced to lead at the cathode and oxidized to solid lead(II) oxide PbO at the anode. Suppose a current of 96.0A is fed into a car battery for 37.0 seconds. Calculate the mass of lead deposited on the cathode of the battery.

Answers

Answer: 3.73 grams

Explanation:

[tex]Q=I\times t[/tex]

where Q= quantity of electricity in coloumbs

I = current in amperes = 96.0 A

t= time in seconds = 37.0 sec

[tex]Q=96.0A\times 37.0s=3552C[/tex]

The reaction at cathode is:

[tex]Pb^{2+}+2e^-\rightarrow Pb[/tex]

[tex]96500\times 2=193000Coloumb[/tex] of electricity deposits 1 mole of  

3552 C of electricity deposits =[tex]\frac{1}{193000}\times 3552=0.018moles[/tex] of Pb

[tex]\text {mass of Pb}={\text{moles}\times {\text{Molar mass}}[/tex]

[tex]\text {mass of Pb}={0.018}\times {207.2g/mol}=3.73g[/tex]

Thus mass of lead deposited is 3.73 g

Do all materials respond to heat in the same way? Give an example to support your answer.

Answers

Answer:

yes.

Explanation:

Energy transfer will continue until the objects are at the same temperature. There are 3 ways in which thermal energy can be transferred from one object/substance to another, or from a system to its surroundings: Conduction. Convection.

All materials do not respond to heat in the same way because every material is made up of different arrangements of atoms and different substances, and different substances respond differently when reacting with heat.

What is heat?

Heat is a form of energy that is produced by the burning of something. It is thermal energy that increases the warmth of a body or an atmosphere.

As long as the objects are not at the same temperature, energy transfer will continue. Three methods exist for transferring thermal energy from one thing or thing to another, or from a system to its surroundings: Conduction. Convection.

Thus, because each material is made up of a unique combination of atoms and substances, and because each substance reacts to heat in a unique way, no two materials react to heat in the same way.

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What is the other product for this reaction? Hbr + NaOH —> ( select 2)

Answers

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Answer: HBr + NaOH = nabr + h2o

Explanation:

I hope this helped!

<!> Brainliest is appreciated! <!>

- Zack Slocum

*☆*――*☆*――*☆*――*☆*――*☆*――*☆*――*☆*――*☆**☆*――*☆*――*☆*――*☆

Predict the empirical formulas of the ionic compounds formed from the following pairs of element. Name each compoun.
A. Li and N.
B. GA and O.
C. Rb and Cl.
D. Ba and S.

Answers

Answer: A.  [tex]LiN_3[/tex] : Lithium (I) nitride.

B. [tex]Ga_2O_3[/tex] : Galium (III) oxide.

C. [tex]RbCl[/tex]: Rubidium (I) chloride.

D. [tex]BaS[/tex] : Barium (II) sulphide.

Explanation:

Empirical formula is the simplest chemical formula which depicts the whole number of atoms of each element present in the compound.  

A. Here metal Li is having an oxidation state of +1 called as [tex]Li^{+}[/tex] cation and [tex]N^{3-}[/tex] is an anion with oxidation state of -3. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]LiN_3[/tex]. The name of the compound is Lithium (I) nitride.

B. Here metal Ga is having an oxidation state of +3 called as [tex]Ga^{3+}[/tex] cation and [tex]O^{2-}[/tex] is an anion with oxidation state of -2. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]Ga_2O_3[/tex]. The name of the compound is Galium (III) oxide.

C. Here metal Rb is having an oxidation state of +1 called as [tex]Rb^{+}[/tex] cation and [tex]Cl^{-}[/tex] is an anion with oxidation state of -1. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]RbCl[/tex]. The name of the compound is Rubidium (I) chloride.

D. Here metal Ba is having an oxidation state of +2 called as [tex]Ba^{+}[/tex] cation and [tex]S^{2-}[/tex] is an anion with oxidation state of -2. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral [tex]BaS[/tex]. The name of the compound is Barium (II) sulphide.

If you just want points just say so this can lead me to failing 10th if I don’t pass this quiz so if you don’t know just say so I understand you want points I just don’t wanna fail Ocean acidification is a consequence that occurs when the equilibrium between CO2
CO
2
concentrations in the ocean and atmosphere starts shifting. What is the pH of pure water?

Question 8 options:

13, basic


7, neutral


4, acidic

Answers

Answer:

13,basic would be your answer!

Explanation:

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