Filling Air Bags Automobile air bags produce nitrogen gas from the reaction:


a. If 2.25 g of NaN3 reacts to fill an air bag, how much P–V work will the N2 do against an external pressure of 1.00 atm given that the density of nitrogen is 1.165 g/L at 20°C?


b. If the process releases 2.34 kJ of heat, what is ∆E for the system?

Answers

Answer 1

(a) The work done by the nitrogen against external pressure is 126.66 J.

(b) The change in the internal energy of the system is -2,466.66 J.

The given parameters:

Mass of the compound, = 2.25 gExternal pressure, P = 1.0 atm = 101325 PaDensity of Nitrogen gas, ρ = 1.165 g/LTemperature of the Nitrogen gas, T = 20⁰C

The molar mass of the given compound is calculated as follows;

NaN₃ = 23+ (14 x 3) = 65 g/mol

65 g -------------- 42

2.25 g ------------- ?

[tex]= \frac{2.25 \times 42}{65} \\\\= 1.45 \ g[/tex]

The volume of the nitrogen gas is calculated as follows;

[tex]\rho = \frac{m}{V} \\\\V = \frac{m}{\rho} \\\\V = \frac{1.45}{1.165} \\\\V = 1.25 \ L[/tex]

[tex]V = 0.00125 \ m^3[/tex]

The work done by the nitrogen against external pressure is calculated as follows;

[tex]W = PV\\\\W = 101325 \times 0.00125\\\\W = 126.66 \ J[/tex]

The change in the internal energy of the system is calculated by applying first law of thermodynamics as follows;

[tex]\Delta E = Q - W\\\\\Delta E = (-2,340) - (126.66)\\\\\Delta E = -2,466.66 \ J[/tex]

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Answer:

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Answers

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Iron because iron is the only one magnetic of the three

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The chemical element iron has the atomic number 26 and the symbol Fe. It is a metal that is found in group 8 of a periodic table and the first transition series. It makes up a large portion of the planet's outer or inner core and is the most prevalent element on Earth by mass, just ahead of oxygen.

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determine the ph of a buffer that is 0.55 M HNO2 and 0.75 M KNO2. tha value of Ka for HNO2 is 6.8*10^-4

Answers

Answer:

pH = 3.3

Explanation:

Buffer solutions minimize changes in pH when quantities of acid or base are added into the mix. The typical buffer composition is a weak electrolyte (wk acid or weak base) plus the salt of the weak electrolyte. On addition of acid or base to the buffer solution, the solution chemistry functions to remove the acid or base by reacting with the components of the buffer to shift the equilibrium of the weak electrolyte left or right to remove the excess hydronium ions or hydroxide ions is a way that results in very little change in pH of the system. One should note that buffer solutions do not prevent changes in pH but minimize changes in pH. If enough acid or base is added the buffer chemistry can be destroyed.

In this problem, the weak electrolyte is HNO₂(aq) and the salt is KNO₂(aq). In equation, the buffer solution is 0.55M HNO₂ ⇄ H⁺ + 0.75M KNO₂⁻ . The potassium ion is a spectator ion and does not enter into determination of the pH of the solution. The object is to determine the hydronium ion concentration (H⁺) and apply to the expression pH = -log[H⁺].

Solution using the I.C.E. table:

              HNO₂ ⇄    H⁺   +   KNO₂⁻

C(i)        0.55M       0M      0.75M

ΔC            -x            +x          +x

C(eq)  0.55M - x       x     0.75M + x    b/c [HNO₂] / Ka > 100, the x can be                                    

                                                             dropped giving ...

           ≅0.55M        x       ≅0.75M        

Ka = [H⁺][NO₂⁻]/[HNO₂] => [H⁺] = Ka · [HNO₂]/[NO₂⁻]

=> [H⁺] = 6.80x010⁻⁴(0.55) / (0.75) = 4.99 x 10⁻⁴M

pH = -log[H⁺] = -log(4.99 x 10⁻⁴) -(-3.3) = 3.3

Solution using the Henderson-Hasselbalch Equation:

pH = pKa + log[Base]/[Acid] = -log(Ka) + log[Base]/[Acid]

= -log(6.8 x 10⁻⁴) + log[(0.75M)/(0.55M)]

= -(-3.17) + 0.14 = 3.17 + 0.14 = 3.31 ≅ 3.3

What is an example of a polar molecule

Question 8 options:

A molecule that is made of ionic bonds like NaCl.


A molecule that is made of covalent bonds like sugar.


A molecule made of covalent bonds that has partial positive and partial negative charges in different areas of the atom.


A molecule made of ionic bonds that has strong positive and strong negative charges in different areas of the molecule.

Answers

Answer:

The two main classes of molecules are polar molecules and nonpolar molecules. Some molecules are clearly polar or nonpolar, while others fall somewhere on the spectrum between two classes. Here's a look at what polar and nonpolar mean, how to predict whether a molecule will be one or the other, and examples of representative compounds.

Explanation:

so its c

An example of polar molecule is a molecule made of covalent bonds that has partial positive and partial negative charges in different areas of the atom.

What is covalent bond?

Covalent bond is defined as a type of bond which is formed by the mutual sharing of electrons to form electron pairs between the two atoms.These electron pairs are called as bonding pairs or shared pair of electrons.

Due to the sharing of valence electrons , the atoms are able to achieve a stable electronic configuration . Covalent bonding involves many types of interactions like σ bonding,π bonding ,metal-to-metal bonding ,etc.

Sigma bonds are the strongest covalent bonds while the pi bonds are weaker covalent bonds .Covalent bonds are affected by electronegativities of the atoms present in the molecules.Compounds having covalent bonds have lower melting points as compared to those with ionic bonds.

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